Design and synthesis of a novel anchoring ligand for highly efficient thin film dye-sensitized solar cells.

نویسندگان

  • Amaresh Mishra
  • Nuttapol Pootrakulchote
  • Markus K R Fischer
  • Cedric Klein
  • Md K Nazeeruddin
  • Shaik M Zakeeruddin
  • Peter Bäuerle
  • Michael Grätzel
چکیده

A novel ligand, 5,5'-(2,2'-bipyridine-4,4'-diyl)-bis(thiophene-2-carboxylic acid) (BTC), and its Ru(II) complex (BTC-1) in which the anchoring group is attached to the thiophene units were developed. Using a low-volatility electrolyte and 3.3 mum mesoporous TiO2 films BTC-1 achieved a solar-to-electricity conversion efficiency of 6.1%, compared to 4.8% for N719 under the same experimental conditions.

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عنوان ژورنال:
  • Chemical communications

دوره 46  شماره 

صفحات  -

تاریخ انتشار 2009